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What is Plasticizers?

Plasticizers are substances added to plastic products to make them soft, flexible, and highly resilient. They are incorporated into the polymer during the plastic manufacturing process to facilitate processes such as drawing, rolling, coating, and high-temperature molding. Plasticizers enhance the plastic’s resistance to acidic and alkaline conditions and improve its durability.

Plasticizers are synthesized from the esterification reaction of acids such as phthalic acid, trimellitic acid, and adipic acid with alcohols like 2-ethylhexanol and isononanol. There are various types of plasticizers with diverse chemical structures, contributing to their varied applications.

Key Considerations in selecting Plasticizers

Key considerations in selecting plasticizers include

  • Compatibility
  • Plasticization efficiency
  • Durability (resistance to abrasion, low solubility, and resistance to oil)
  • Resistance to cold, heat, weather conditions
  • Electrical insulation

The choice of plasticizer is crucial in industries producing plastic products for food and pharmaceuticals, medical instruments, children’s toys, construction materials, automotive parts, and electrical cables. Sometimes added to improve melting processability of PVC and other polymers such as acrylic, polypropylene (PP), polyethylene (PE), polyethylene terephthalate (PET) and polyurethane (PU)

Plasticizers can be classified into two main types:

1. PRIMARY PLASTICIZER

These are general-purpose plasticizers used to enhance the flexibility, softness, and moldability of plastics. Examples include such as diisononyl phthalate (DINP), di(2-propylheptyl) phthalate (DPHP), and di(2-ethylhexyl) phthalate (DEHP or DOP), Tri (2-ethylhexyl) phthalate (TOTM), Di (2-ethylhexyl) Terephthalate (TOTM).

These plasticizers are often used in higher concentrations to achieve the desired flexibility and softness in plastic products.

2. SECONDARY PLASTICIZER

These are often used in combination with primary plasticizers to tailor specific properties of the plastic material, such as improved resistance to cold, enhanced heat stability, or reduced volatility. Examples include adipates like di(2-ethylhexyl) adipate (DOA) and bio-based plasticizers like epoxidized soybean oil (ESBO).

These secondary plasticizers are used in smaller amounts to achieve specific performance targets in the final product.

Application of plasticizers

Category Name Acronym Applications
Trimellitate Tris-2-ethylhexyl trimellitate TOTM Cables and wires, Film and sheet, Medical Applications
Terephthalate Dioctyl terephthalate DOTP/DEHT/DEHTP Flooring, Food packaging – Cling Wrap, Toys, Medical Applications
Other ester 2,2,4-trimethyl-1,3 pentanediol di-isobutyrate TXIB Flooring, Adhesives & Sealants, Toys
Ortho-phthalate Di(2-propyl heptyl) phthalate DPHP Flooring, Wall coverings, Cladding and Roofing, Cables and wires, Film and sheet, Automotive, Tubes & Hoses, Coated Fabrics
  (second DINP line)    
Ortho-phthalate Diisononyl phthalate DINP Flooring, Wall coverings, Cladding and Roofing, Cables and wires, Film and sheet, Automotive, Tubes & Hoses, Coated Fabrics, Inks and waxes
Ortho-phthalate Bis(2-ethylhexyl) phthalate DEHP PVC sheet Film Leather
Wire & Cable insulation
Paint
Ortho-phthalate Di-n-butyl phthalate DBP Flooring, Automotive, Inks and waxes
Epoxy ester Epoxidised soybean oil ESBO Automotive, Food packaging – Cling Wrap
Adipate Di-2-ethylhexyl adipate DEHA/DOA Flooring, Wall coverings, Cladding and Roofing, Film and sheet, Automotive, Tubes & Hoses, Coated Fabrics, Inks and waxes, Food packaging – Cling Wrap, Toys

 

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